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Synthesis and Characterization of New Unsymmetrically Substituted Phthalocyanines

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 Unsymmetric metallophthalocyanines (M=Zn, Co, Ni) carrying alkylthio and acetyloxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The extremely soluble compounds were characterized by their IR, 1H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.

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Authors and Affiliations

  1. Technical University of İstanbul, Department of Chemistry, TR-80626 Maslak, İstanbul, Turkey, , , , , , TR

    Süleyman Gürsoy, Zehra A. Bayır, Esin Hamuryudan & Özer Bekarogğlu

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  1. Süleyman Gürsoy
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  2. Zehra A. Bayır
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  3. Esin Hamuryudan
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  4. Özer Bekarogğlu
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Received July 27, 1999. Accepted (revised) September 30, 1999

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Gürsoy, S., Bayır, Z., Hamuryudan, E. et al. Synthesis and Characterization of New Unsymmetrically Substituted Phthalocyanines. Monatshefte für Chemie 131, 287–292 (2000). https://doi.org/10.1007/s007060070104

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  • DOI: https://doi.org/10.1007/s007060070104

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